DSpace コレクション: 1980-071980-07http://hdl.handle.net/10069/239112019-02-21T01:57:48Z2019-02-21T01:57:48ZReduction of Carbonyl and Related Compounds by an Acid-Stable NADH Analogue plus Bronsted AcidShinkai, SeijiHamada, HisatakeManabe, Osamuhttp://hdl.handle.net/10069/239922012-01-26T06:48:08Z2010-09-17T04:44:29Zタイトル: Reduction of Carbonyl and Related Compounds by an Acid-Stable NADH Analogue plus Bronsted Acid
著者: Shinkai, Seiji; Hamada, Hisatake; Manabe, Osamu
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.109-113; 1980
抄録: Reduction of C=C, C=O, and C=N double bonds by an acid-stable NADH analogue, 3-aminocarbonyl-N-benzyl-1, 4-dihydroquinoline (BzlQH) was reported. BzlQH reduced β-nitrostyrene in 28% yield and pyridine-2-aldehyde and the Schiff base in relatively high yields (58-85%) in the presence of Brφnsted acids. In all the cases, the yield is superior to that by N-benzyl-1, 4-dihydronicotinamide under the comparable reaction conditions. The results indicate that the reduction reaction by BzlQH is largely improved by added Brφnsted acids. The role of added acids was discussed in relation to the efficiency of enzymatic catalysis.2010-09-17T04:44:29ZSorption and Diffusion of Normal Hydrocarbons in Natural RubberKawakami, MitsuyasuKagawa, Shuichihttp://hdl.handle.net/10069/239912012-01-26T06:48:08Z2010-09-17T04:41:04Zタイトル: Sorption and Diffusion of Normal Hydrocarbons in Natural Rubber
著者: Kawakami, Mitsuyasu; Kagawa, Shuichi
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.101-108; 1980
抄録: Solubility and diffusion coefficients of normal C2-C6 hydrocarbons in unvulcanized natural rubber have been determined. Data on concentration dependence of the solubility constant could be correlated by S=S0 exp(αc) and the parameter α are related to the Flory-Huggins interaction parameter χ approximately by α=2χ+1. The concentration dependence of diffusion coefficient are fitted by the expression D=D0(1-αc) exp (βc) derived from a first-approximation free volume theory. The diffusion coefficient, D0 extrapolated to zero concentration and its activation energy decrease with increasing molecular size up to C3 and reach a constant value for C4 and higher hydrocarbons. The parameter β is almost constant for C4-C6 hydrocarbons. It is demonstrated that these hydrocarbons would move through polymeric media like a needle in concert with the thermal motion of polymer segments and only the free volumes larger than the effective cross-sectional diameter of the diffusant molecule is available for diffusion.2010-09-17T04:41:04ZPPG-TDI-BDポリウレタン網目の分析古川, 睦久http://hdl.handle.net/10069/239902012-01-26T06:48:08Z2010-09-17T04:31:51Zタイトル: PPG-TDI-BDポリウレタン網目の分析
著者: 古川, 睦久
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.95-100; 1980
抄録: Methods for the determination of the degree of crosslinking and the number of effective chains per unit volume in polyurethane networks have been described. The methods are as follws; 1) calculation from stoichiometry, 2) calculation from molecular weight of linear polyurethanes which were obtained by the degradation of crosslink site of cured polyurethane, 3) calculation from amine degradation, and 4) calculation from Young's modulus. The allophanate-cured polyurethanes prepared from PPG, TDI, and 1, 4-butanediol have been used as model networks in order to ascertain the validity of these methods. The parameters of network structure calculated from the experimental methods are lower than those from stoichiometry. The parameters calculated from method 2 and 3 were fairly close to those from Young's moduli. The properties of the primary chains which were the starting and the intermediate materials for preparing polyurethane networks have been studied with GPC, HPLC, IR, and UV.2010-09-17T04:31:51Z酸溶液中のニッケル上での電解水素の発生，透過坂本, 芳一三浦, 晃http://hdl.handle.net/10069/239892012-01-26T06:48:08Z2010-09-17T04:29:50Zタイトル: 酸溶液中のニッケル上での電解水素の発生，透過
著者: 坂本, 芳一; 三浦, 晃
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.87-94; 1980
抄録: The investigation of the electrolytic hydrogen evolution reaction on nickel has been carried out in both H2S04a nd HCl solutions, using permeation-potential and current-potential relationships as a diagnostic criterion for mechanism determination. The mechanism for hydrogen evolution reaction on nickel in both solutions, regardless of the addition of H2SeO3 is a "Slow discharge-fast recombination", not depending upon pH values. However, the experimental results could not distinguish that the mode of adsorption of hydrogen is either the Langmuir or Temkin type. The effect of addition of H2SeO3 may be aUributed not to so much the lowering the binding energy of M-Hads bond as the increase of the entropy change of adsorbed hydrogen atoms.2010-09-17T04:29:50Z砂の弾塑性挙動について棚橋, 由彦内藤, 秀信永尾, 光也東川, 一則http://hdl.handle.net/10069/239882012-01-26T06:48:08Z2010-09-17T04:27:48Zタイトル: 砂の弾塑性挙動について
著者: 棚橋, 由彦; 内藤, 秀信; 永尾, 光也; 東川, 一則
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.79-86; 1980
抄録: A Sand is such a complex material that is initiated dilatancy with loading and is largely influenced by stress histories. In the previous paper, an incremental stress-strain relationship was proposed which was given in terms of tensor considering the subsequent anisotropy of Sands. But it had a tendency to overestimate observed extensive dilatancy and it could not calculate stress strain behaviour of Sands under both unloading and reloading. So newly in this paper, an elasto-plastic stresss strain relationship (constitutive equation) is proposed considering a Sand as strain hardening material not only for shear but for compression, by adopting stress-dilatancy equation which is widely admitted in the field of soil engineering. And some stress path tests of Toyoura Sand are carried out for the verification of the proposed equation. As the results of the comparison of both obsreved and calculated values of the strains along with some stress paths subjected complex stress histories, it was acertained that the proposed equation estimates reasonably the elasto-plastic stress strain behaviour of Sands.2010-09-17T04:27:48ZUNDRAINED STRENGTH OF NORMALLY CONSOLIDATED CLAY MEASURED IN THE SIMPLE SHEAR TESTOchiai, Hidetoshihttp://hdl.handle.net/10069/239872011-10-18T08:56:32Z2010-09-17T04:25:09Zタイトル: UNDRAINED STRENGTH OF NORMALLY CONSOLIDATED CLAY MEASURED IN THE SIMPLE SHEAR TEST
著者: Ochiai, Hidetoshi
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.73-78; 1980
抄録: This paper discusses a method for calculating the "true" undrained strength ratio, (cu/p)ss, and the internal friction angle, φ'ss, in terms of effective stress of normally consolidated clays measured in a simple shear test. The proposed method consists in assuming that the directions of the principal stress axes during the simple shear test are expressed by the relation proposed by Oda and Konishi. Experimental results obtained from three types of clays confirm that the method gives more reasonable estimates of (cu/p)ss and φ'ss for normally consolidated clay compared to other methods. The method also supports Ladd's statement that (cu/p)ss should generally be less than (cu/p)TC determined from the triaxial compression test due to undrained strength anisotropy. Finally, a significant disadvantage of the method proposed by Duncan and Dunlop is discussed, and it is pointed out that the Duncan and Dunlop method may predict excessively high values of φ'ss for normally consolidated clay.2010-09-17T04:25:09Z強混合型感潮河川における塩分濃度分布の一解析法古本, 勝弘藤沢, 弘明http://hdl.handle.net/10069/239842012-01-26T06:48:08Z2010-09-17T02:45:06Zタイトル: 強混合型感潮河川における塩分濃度分布の一解析法
著者: 古本, 勝弘; 藤沢, 弘明
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.65-72; 1980
抄録: An analytical expedient for salinity intrusion of well-mixed estuaries is to solve one dimensional convective diffusion equation in any kind of way. As the stream of estuary is unsteady due to tide and the flow area is nonuniform in longitudinal direction, the flow velocity, the cross sectional area and the dispersion coefficient in estuary vary with time and position. Therefore it is very difficult to solve analytically the convective diffusion equation which has these functions of time and position for hydraulic coefficients. In this paper the complex problems are made simple as follows, solving the equation of salinity convective diffusion in estuaries. Considering that the diffusion equation holds good averagely during a tidal cycle and solving the diffusion equation in wihch velocity is transformed into constant river discharge velocity, longitudinal salinity distribution at low tide slack is determined. Next, the salinity distribution at low tide slack is carried through the estuary by means of tidal velocity. The solutions obtained by this method are presented and are applied in the Chikugo River. The analytical results show fairly good agreement with the field observed data.2010-09-17T02:45:06Z鋼製高橋脚の耐震最適設計小西, 保則高橋, 和雄新井, 伸博http://hdl.handle.net/10069/239832012-01-26T06:48:08Z2010-09-17T02:37:17Zタイトル: 鋼製高橋脚の耐震最適設計
著者: 小西, 保則; 高橋, 和雄; 新井, 伸博
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.57-64; 1980
抄録: Optimum aseismic design of high steel pier with circular cross-section is presented. The pier is idealdzed by a cantilever with end spring and mass subjected to axial force. The methed of modal analysis and root mean square method are employed to determine earthquake response of the structure. SUMT method is used in the optimum design. N umerical results are shown for the high steel pier which supports two spans continuous truss.2010-09-17T02:37:17Z初期不整を有する平板構造の最終強度（その2）有孔平板河角, 省治福地, 信義南, 美隆http://hdl.handle.net/10069/239822011-10-18T08:55:48Z2010-09-17T02:34:37Zタイトル: 初期不整を有する平板構造の最終強度（その2）有孔平板
著者: 河角, 省治; 福地, 信義; 南, 美隆
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.47-56; 1980
抄録: For weight saving, access and piping, many holes are made on plate structure such as a ship hull and as teel girder bridge. In addition to the existence of hole, the ultimate strength of plate is decreased by initial imperfections caused by the application of welding and gas cutting to fabricate it. And the collapsed failure of such a structure has not ceased to exist. In this report, the numerical analyses of perforated plates with initial deflection subjected to in-plane compression are carried by mentioned means in first report. The deforming behavier, extension of yielding region, collapsed load and collapsed mode on the plate with a hole are investigated. By the results of those analyses, the relations between ultimate strength and mode or value of initial deflection or hole diameter are clarified. Furthermore, the empirical formula on the ultimate strength of perforated plate with initial deflection are introduced for practical use.2010-09-17T02:34:37Z鉄塔ネックフランジ溶接継手部の破壊靱性把握とその評価に関する研究黒川, 常夫片岡, 繁夫河野, 和芳岡, 延夫http://hdl.handle.net/10069/239812011-10-18T08:55:19Z2010-09-17T02:26:19Zタイトル: 鉄塔ネックフランジ溶接継手部の破壊靱性把握とその評価に関する研究
著者: 黒川, 常夫; 片岡, 繁夫; 河野, 和芳; 岡, 延夫
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.39-46; 1980
抄録: Recently, transmission steel tower has been increasing and welded Neck Flange joint has been applied steel tower for post joint. However, welding process has a somewhat undesirable effect of adversely affecting the toughness of the weld bond at welded joints. In order to secure the safety of steel tower, therefor, the study on fracture toughness welded Neck Flange joint is one of important problems. In this experiment, the authors carried out COD bend test with weld test specimens of SM 4IB and STK 55 steels which were welded using CO2 arc process. From the results of these tests, the characteristics of fracture toughness were evaluated on the welded Neck Flange joint.2010-09-17T02:26:19Z複合非線形性を有する薄肉閉断面はりの一解析法栗原, 和夫崎山, 毅http://hdl.handle.net/10069/239802012-01-26T06:48:08Z2010-09-17T02:23:56Zタイトル: 複合非線形性を有する薄肉閉断面はりの一解析法
著者: 栗原, 和夫; 崎山, 毅
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.29-38; 1980
抄録: This paper presents a method of analysis of elastic-plastic finite displacement problems of thin walled curved beams. The fundamental equilibrium equations are obtained from the principle of incremental virtual work. Based on the discrete general solution of fundamental differential equation, the geometrical and material nonlinearities are analyzed by incrementalload procedure (step by step method) and tangent modulus theory. As the result of numerical analysis, the propriety of the present method was verfied.2010-09-17T02:23:56Z逆アセンブラの試作鶴丸, 弘昭吉田, 博美高倉, 聡http://hdl.handle.net/10069/239792012-01-26T06:48:08Z2010-09-17T02:21:54Zタイトル: 逆アセンブラの試作
著者: 鶴丸, 弘昭; 吉田, 博美; 高倉, 聡
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.23-28; 1980
抄録: This paper is concerned with the design and implementation of the inverse assembler which is used for analyzing MELCOM-70system programs. The inverse assembler translates machine-code programs into symbolic assembly language. It works on a two-pass basis, that is, it makes two scans of the machine-code program. The first pass builds up a symbol table by collecting internal symbols and external symbols, and the second pass does the actual translation, using the internal and external symbols generated in the first pass. The inverse assembler designed here has the following four features. 1. The generated internal symbols represent a certain content of each address. 2. User is able to use fifty external symbols which fit a content of each address. 3. Series internal symbols are generated even to a program separated into two segments. 4. The data word is converted into a number of four hexadecimal digits.2010-09-17T02:21:54Z佐世保湾の流動および拡散に関する研究（第3報 数値計算による潮流シミュレーション）宇都, 幸一栗須, 正登中根, 重勝野中, 稀平http://hdl.handle.net/10069/239782012-01-26T06:48:08Z2010-09-17T02:19:37Zタイトル: 佐世保湾の流動および拡散に関する研究（第3報 数値計算による潮流シミュレーション）
著者: 宇都, 幸一; 栗須, 正登; 中根, 重勝; 野中, 稀平
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.17-22; 1980
抄録: Experimental studies on the Current by Hydraulic Model is reported in the first report. In this paper, the Tidal Current in Sasebo Bay is sumulated by finite different method. The solutions obtained therefrom are as follows, (a) The Tidal Current in Sasebo Bay is powerful from the entrance of Sasebo Bay to Omura Bay. (b) The result by Hydraulic Model and that by the numerical method are compared. When outward flow from Sasebo Bay it can be seem strong V ortexes in Hydraulic model at the entrance of the Bay while calculation resu1t does not. Althought, the both of the main current pattern are same.2010-09-17T02:19:37Z佐世保湾の流動および拡散に関する研究（第2報：水理模型による拡散実験）田中, 清裕中根, 重勝栗須, 正登http://hdl.handle.net/10069/239772012-01-26T06:48:08Z2010-09-17T02:16:49Zタイトル: 佐世保湾の流動および拡散に関する研究（第2報：水理模型による拡散実験）
著者: 田中, 清裕; 中根, 重勝; 栗須, 正登
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.9-16; 1980
抄録: In this paper, we reported studies on diffusion of sea pollution in the Sasebo Bay the Hydralic model. We used uranin (dyestuffs) as diffusion tracer and the following positions were selected as test points. They are (1) Kogosaki (2) Saikaibashi (3) River Sasebo (4) River Hiu. We obtained experimental data on diffusion patterns from the test positions above mentioned and clarified sea polution in the Sasebo Bay experimentally.2010-09-17T02:16:49Z腰幅をもつ2脚モデルの歩行眞武, 友一今井, 康文御手洗, 忠http://hdl.handle.net/10069/239762012-01-26T06:48:08Z2010-09-17T02:14:31Zタイトル: 腰幅をもつ2脚モデルの歩行
著者: 眞武, 友一; 今井, 康文; 御手洗, 忠
発行日: 1980-07
引用: 長崎大学工学部研究報告, (15), pp.1-8; 1980
抄録: A new bipedal walking model has been proposed and the walking motion of the model has been analyzed. The model has a waist width and hence provides more realistic information of the human gait than the old model does. The model consists of two masses located at a waist region and rigid links corresponding to the thighs, low legs, and feet, jointed by pins together with torsional springs. Difference from the old model is the following : Two hip joints are separated for a waist width and are connected to the femoral region of each leg with torsional springs. The old model has no waist width and hence that walking motion is restricted on one vertical plane. On this new model, however, the walking motion is allowed in two vertical planes. Therefore, the waist swings sinusoidally in a holizontal plane during walking. In almost investigations of a human walking, it seems that attention is focused on the method of optimum control of the driving force or torque in order to attain a normal gait. In this investigation, on the other hand, driving force is only a waist swing which is not controlled. Only thing to do is to choose the appropriate spring constants so that the normal walking is possible.2010-09-17T02:14:31Z