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Efficient Oxidation of Adamantanes by Sodium Nitrite with Molecular Oxygen in Trifluoroacetic Acid


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Title: Efficient Oxidation of Adamantanes by Sodium Nitrite with Molecular Oxygen in Trifluoroacetic Acid
Authors: Onomura, Osamu / Yamamoto, Yutaka / Moriyama, Noriaki / Iwasaki, Fumiaki / Matsumura, Yoshihiro
Issue Date: Jun-2006
Publisher: Thieme
Citation: Synlett 15, pp.2415-2418 : 2006
Abstract: Oxidation of adamantanes by oxygen was effectively achieved by use of sodium nitrite as a catalyst in trifluoroacetic acid (TFA) to give 1-adamantyl trifluoroacetates, from which adamantanols were obtained in good yields. A catalytic amount of sodium nitrite was essential and TFA was the best solvent among solvents examined for this oxidation.
Keywords: alcohols / hydrocarbons / oxidations / oxygen / radical reactions
URI: http://hdl.handle.net/10069/16399
ISSN: 09365214
DOI: 10.1055/s-2006-950422
Rights: (c) Georg Thieme Verlag KG Stuttgart New York. All rights reserved.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/16399

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