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Asymmetric Introduction of Nucleophiles to the 2-Position of Pyrrolidine Ring through N-Acylpyrrolidinium Ion


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Title: Asymmetric Introduction of Nucleophiles to the 2-Position of Pyrrolidine Ring through N-Acylpyrrolidinium Ion
Authors: Onomura, Osamu / Ikeda, Takashi / Matsumura, Yoshihiro
Issue Date: 31-Dec-2005
Publisher: Institute of Heterocyclic Chemistry
Citation: Heterocycles, Vol. 66, 81-86 (2005)
Abstract: Asymmetric carbon-carbon bond-forming reaction at the 2-position of a pyrrolidine ring was achieved. The reaction involved a chiral Ti(IV) catalyzed coupling between 1-methoxycarboyl-2-methoxypyrrolidine and silyl enol ethers to afford 2-substituted pyrrolidines with up to 53 % ee.
URI: http://hdl.handle.net/10069/16411
ISSN: 03855414
Rights: Copyright © 2008 The Japan Institute of Heterocyclic Chemistry
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/16411

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