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Asymmetric electrochemical oxidation of 1,2-diols, aminoalcohols and aminoaldehydes in the presence of chiral copper catalyst


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Title: Asymmetric electrochemical oxidation of 1,2-diols, aminoalcohols and aminoaldehydes in the presence of chiral copper catalyst
Authors: Minato, Daishirou / Arimoto, Hitomi / Nagasue, Yoko / Demizu, Yosuke / Onomura, Osamu
Issue Date: 7-Jul-2008
Publisher: Pergamon Press Ltd.
Citation: Tetrahedron, 64(28), pp.6675-6683; 2008
Abstract: Asymmetric oxidation of 1,2-diols, aminoalcohols and aminoaldehydes in the presence of copper(II) triflate and (R,R)-Ph-BOX, was accomplished by electrochemical method using Br- as a mediator. This oxidation was applicable to kinetic resolution of racemic cis-cycloalkane-1,2-diols, aminoalcohols and aminoaldehydes to afford optically active compounds with good to high enantioselectivity.
Keywords: 1,2-Diol / α-Ketoalcohol / Aminoalcohol / Aminoaldehyde
URI: http://hdl.handle.net/10069/16985
ISSN: 00404020
DOI: 10.1016/j.tet.2008.05.015
Rights: Copyright (c) 2008 Elsevier Ltd All rights reserved.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/16985

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