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無機クロマトグラフに関する研究(第2報) アルミナによる陰イオンの簡易微量分析並びに金属錯塩のクロマトグラフ約分灘について

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タイトル: 無機クロマトグラフに関する研究(第2報) アルミナによる陰イオンの簡易微量分析並びに金属錯塩のクロマトグラフ約分灘について
その他のタイトル: Studies on the Inorganic Chromatography.Ⅱ. A Conyenient Microanalysis of Anions with Alumina and Chromatographic Separation of Metal Complexes.
著者: 安永, 峻五 / 下村, 脩
著者(別表記) : Yasunaga, Shungo / Shimomura, Osamu
発行日: 1953年12月
出版者: 日本薬学会 / the Pharmaceutical Society of Japan
引用: 薬学雑誌, 73(12), pp.1350-1353; 1953
抄録: By the use of the same method of capillary filled with alumina as given in the previous paper, order of adsorption, limit of detection, separation of several kinds of anions, and the method of microdetection of I-, NO2-, and CN-ions were examined. It was found that the separations of Cl- and PO4---, Cl-and AsO4---, PO4--- and AsO4----,AsO3---and AsO4---, I-, CrO4--, and PO4---, NO2- and CrO4--, were possible. The coloration reagents used were, besides the known AgNO3 method, CuCl2, Hg(NO3)2, FeCl3, and benzidine. Chromatographic separation of metal complexes were also carried out by the same method and the separation of Cr and Pb, which was previously reported as being comparatively difficult was found to be possible by preparing a tartaric acid complex, while that of cobalt, nickel, and cadmium was found to be possible by the ammonium complex method.
URI: http://hdl.handle.net/10069/20873
ISSN: 00316903
資料タイプ: Journal Article
原稿種類: publisher

引用URI : http://hdl.handle.net/10069/20873



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