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Catalytic monoalkylation of 1,2-diols


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Title: Catalytic monoalkylation of 1,2-diols
Authors: Maki, Toshihide / Ushijima, Nobuto / Matsumura, Yoshihiro / Onomura, Osamu
Issue Date: Apr-2009
Publisher: Elsevier
Citation: Tetrahedron Letters, 50(13), pp.1466-1468; 2009
Abstract: A catalytic monoalkylation of 1,2-diols by using a weak base has been developed. Copper(II) dichloride and boronic acids are effective catalysts for activating 1,2-diols in the presence of potassium carbonate as a base. Various 1,2-diols were selectively monoalkylated with allyl-, benzyl- and alkyl- halides in DMF by choosing a suitable catalyst for each 1,2-diols.
Keywords: Diol / Alkylation / Lewis acid / Allylation / Benzylation
URI: http://hdl.handle.net/10069/20916
ISSN: 00404039
DOI: 10.1016/j.tetlet.2009.01.063
Rights: Copyright © 2009 Elsevier Ltd All rights reserved.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/20916

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