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Nonenzymatic kinetic resolution of 3-hydroxyalkanamides with chiral copper catalyst


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Title: Nonenzymatic kinetic resolution of 3-hydroxyalkanamides with chiral copper catalyst
Authors: Demizu, Yosuke / Kubo, Yuki / Matsumura, Yoshihiro / Onomura, Osamu
Issue Date: 12-Feb-2008
Publisher: Thieme
Citation: Synlett, 3, pp.433-437; 2008
Abstract: Kinetic resolution of 3-hydroxyalkanamides with good to high selectivities was achieved by benzoylation using copper(II) triflate and (R,R)-PhBox [2,2′-isopropylidenebis(4-phenyl-2-oxazoline)] as catalyst, which also mediated enantioselective tosylation of 2,2-bis(hydroxymethyl)alkanamides with high efficiency.
Keywords: 3-hydroxyalkanamides / Acylations / Chiral copper complex / Kinetic resolution / Molecular recognition
URI: http://hdl.handle.net/10069/20918
ISSN: 09365214
DOI: 10.1055/s-2008-1032057
Rights: (c) Georg Thieme Verlag KG Stuttgart New York. All rights reserved.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/20918

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