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Ring Contraction of α,β-Unsaturated Cyclic Amines with cis-Dihydroxylation at the α,β-Position


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Title: Ring Contraction of α,β-Unsaturated Cyclic Amines with cis-Dihydroxylation at the α,β-Position
Authors: Onomura, Osamu / S. Libendi, Samuel / Demizu, Yosuke / Matsumura, Yoshihiro
Issue Date: Jan-2009
Publisher: The Japan Institute of Heterocyclic Chemistry
Citation: Heterocycles, 77 (1), pp.311-321; 2009
Abstract: α,β-Unsaturated cyclic amines are oxidized by OsO4 to afford α,β-cis-dihydroxylated compounds which are thermodynamically transformed into ring-opened keto-alcohols. The keto-alcohols are then cyclized to form synthetically useful ring-contracted cyclic amines.
URI: http://hdl.handle.net/10069/21990
ISSN: 03855414
DOI: 10.3987/COM-08-S(F)18
Rights: Copyright © 2009 The Japan Institute of Heterocyclic Chemistry
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/21990

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