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Nonenzymatic kinetic resolution of racemic α-hydroxyalkanephosphonates with chiral copper catalyst


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Title: Nonenzymatic kinetic resolution of racemic α-hydroxyalkanephosphonates with chiral copper catalyst
Authors: Demizu, Yosuke / Moriyama, Atsushi / Onomura, Osamu
Issue Date: 16-Sep-2009
Publisher: Elsevier BV
Citation: Tetrahedron Letters, 50(37), pp.5241-5244; 2009
Abstract: Kinetic resolution of α-hydroxyalkanephosphonates was efficiently performed by benzoylation in the presence of copper(II) triflate and (R,R)-Ph-BOX as a catalyst with excellent s value of up to 286.
Keywords: α-Hydroxyalkanephosphonates / Asymmetric benzoylation / Chiral copper complex / Kinetic resolution / Molecular recognition
URI: http://hdl.handle.net/10069/22171
ISSN: 00404039
DOI: 10.1016/j.tetlet.2009.07.003
Rights: © 2009 Elsevier Ltd. All rights reserved.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/22171

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