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PbO-B_2O_3系及びR_2O-PbO-B_2O_3系(R=K or Na)ガラス中のVO^<2+>の光吸収スペクトルとPb原子の存在形態の研究

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Title: PbO-B_2O_3系及びR_2O-PbO-B_2O_3系(R=K or Na)ガラス中のVO^<2+>の光吸収スペクトルとPb原子の存在形態の研究
Other Titles: Studies on Optical Absorption Spectra of VO^<2+> Ions in PbO-B_2O_3 and R_2O-PbO-B_2O_3(R=K or Na)Glasses and Bonding Mode of Pb Atoms in these Glasses
Authors: 古賀, 秀人 / 小池, 隆 / 内山, 休男 / 羽坂, 雅之
Authors (alternative): Koga, Hodeto / Koike, Takashi / Uchiyama, Yasuo / Hasaka, Masayuki
Issue Date: Nov-1986
Publisher: 日本セラミックス協会 / The Ceramic Society of Japan
Citation: 窯業協会誌, 94(1095), pp.1125-1130; 1986
Abstract: The optical absorption spectra of VO2+ ions dissolved in PbO-B2O3 and R2O-PbO-B2O3 glasses (R=K or Na) have been measured. By using the spectral results, the bonding mode of Pb in the glasses has been disussed. Judging from the dependence of peak position for B*2-E*n transition on the glass composition, it is suggested that although Pb behaves as a network modifier in the glasses, a part of Pb contributes to the formation of glass network. This relation is discussed on the basis of the relation between the peak wave number and ratio of four-coordinated B atoms to the total B atoms (N4B). On the assumption that the Pb ratio used in the formation of the glass network is α(x-0.2) in xPb(1-x)B2O3 glasses and (x+y-0.2) in xR2OyPbO(1-x-y)B2O3 glasses, the value of α is calculated to be 2.04.
Keywords: PbO-B_2O_3 glasses / R_2O-PbO-B_2O_3 glasses / Glass structure / Optical spectra / Vanadyl ion / Color indicator / Bonding mode (Pb and R (=K and Na))
URI: http://hdl.handle.net/10069/23584
ISSN: 00090255
Relational Links: http://ci.nii.ac.jp/naid/110002316784/
Rights: 社団法人日本セラミックス協会 / 本文データは学協会の許諾に基づきCiNiiから複製したものである
Type: Journal Article
Text Version: publisher
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/23584

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