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Reduction of Carbonyl and Related Compounds by an Acid-Stable NADH Analogue plus Bronsted Acid


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Title: Reduction of Carbonyl and Related Compounds by an Acid-Stable NADH Analogue plus Bronsted Acid
Authors: Shinkai, Seiji / Hamada, Hisatake / Manabe, Osamu
Issue Date: Jul-1980
Publisher: 長崎大学工学部 / Faculty of Engineering, Nagasaki University
Citation: 長崎大学工学部研究報告, (15), pp.109-113; 1980
Abstract: Reduction of C=C, C=O, and C=N double bonds by an acid-stable NADH analogue, 3-aminocarbonyl-N-benzyl-1, 4-dihydroquinoline (BzlQH) was reported. BzlQH reduced β-nitrostyrene in 28% yield and pyridine-2-aldehyde and the Schiff base in relatively high yields (58-85%) in the presence of Brφnsted acids. In all the cases, the yield is superior to that by N-benzyl-1, 4-dihydronicotinamide under the comparable reaction conditions. The results indicate that the reduction reaction by BzlQH is largely improved by added Brφnsted acids. The role of added acids was discussed in relation to the efficiency of enzymatic catalysis.
URI: http://hdl.handle.net/10069/23992
ISSN: 02860902
Type: Departmental Bulletin Paper
Text Version: publisher
Appears in Collections:No.15

Citable URI : http://hdl.handle.net/10069/23992

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