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キノリル基を末端に持つ非環状光応答イオノファー


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Title: キノリル基を末端に持つ非環状光応答イオノファー
Other Titles: Photoresponsive Podands with Quinolyl Groups at Chain Ends
Authors: 本多, 義弘 / 新海, 征治 / 真鍋, 修
Authors (alternative): Honda, Yoshihiro / Shinkai, Seiji / Manabe, Osamu
Issue Date: Jan-1984
Publisher: 長崎大学工学部 / Faculty of Engineering, Nagasaki University
Citation: 長崎大学工学部研究報告, 14(22), pp.85-90; 1984
Abstract: Photofunctional azobenzenes connected through two polyoxyethylene chains with terminal quinolyl groups were synthesized. These photoresponsive podands (1 and 2) showed high ion-affinity with heavy metal ions such as Cu2+, Hg2+, Pb2+, etc. and moderate affinity with alkali metal ions. 2 having two trioxyethylene chains showed the higher extractabilities (Ex %) than 1 having two dioxyethylene chains. Photo-induced trans-to-cis isomerization and thermal cis-to-trans isomerization occurred reversibly. Significant photo-improvement in Ex% was observed for extraction of Ni2+ and Pb2+ with 1 but not for extraction with 2.
URI: http://hdl.handle.net/10069/24134
ISSN: 02860902
Type: Departmental Bulletin Paper
Text Version: publisher
Appears in Collections:Volume 14, No. 22

Citable URI : http://hdl.handle.net/10069/24134

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