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Amphiphilic Allylic Alkylation with Allyl Alcohols Promoted by Pd-Catalyst and Triethylborane

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Title: Amphiphilic Allylic Alkylation with Allyl Alcohols Promoted by Pd-Catalyst and Triethylborane
Authors: Kimura, Masanari / Tamaru, Yoshinao
Issue Date: 1-Nov-2009
Publisher: Bentham Science Publishers
Citation: Mini-Reviews in Organic Chemistry, 6(4), pp.392-397, 2009
Abstract: The combination of Pd catalyst and triethylborane induces allylic alcohols to undergo direct electrophilic allylation of soft nucleophiles. Similar conditions also accelerate nucleophilic allylations of aldehydes and aldimines to provide homoallyl alcohols and homoallylamines, respectively. Moreover, 2-methylenepropane-1,3-diol undergoes a sequential amphiphilic activation to react with aldehydes and aldimines, giving rise to 3-methylenecyclopentanols and 3-methylenepyrrolidines.
Keywords: Allyl alcohol / Amphiphilic allylation / Palladium / Pyrrolidine / Triethylborane
URI: http://hdl.handle.net/10069/24407
ISSN: 1570193X
DOI: 10.2174/157019309789371631
Rights: © 2009 Bentham Science Publishers Ltd.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/24407

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