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Nucleophilic allylation of N,O-acetals with allylic alcohols promoted by Pd/Et3B and Pd/Et2Zn systems


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Title: Nucleophilic allylation of N,O-acetals with allylic alcohols promoted by Pd/Et3B and Pd/Et2Zn systems
Authors: Yamaguchi, Yumi / Hashimoto, Mariko / Tohyama, Katsumi / Kimura, Masanari
Issue Date: 23-Feb-2011
Publisher: Elsevier Ltd
Citation: Tetrahedron Letters, 52(8), pp.913-915; 2011
Abstract: Pd/Et3B and Pd/Et2Zn systems promote the nucleophilic allylations of 2-aminotetrahydrofuran and 2-aminotetrahydropyran with allylic alcohols to provide ω-hydroxyhomoallylamines in high yields. The transformation is applicable to the allylation of non-protective carbohydrates, such as ribose and deoxyribose.
Keywords: Palladium / Allylation / Hemiacetal / Umpolung / Carbohydrate
URI: http://hdl.handle.net/10069/24970
ISSN: 00404039
DOI: 10.1016/j.tetlet.2010.12.064
Rights: Copyright © 2010 Elsevier Ltd All rights reserved.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/24970

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