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Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: completion of NO reduction cycle.


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Title: Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: completion of NO reduction cycle.
Authors: Arikawa, Yasuhiro / Matsumoto, Naoki / Asayama, Taiki / Umakoshi, Keisuke / Onishi, Masayoshi
Issue Date: 14-Mar-2011
Publisher: Royal Society of Chemistry
Citation: Dalton Transactions, 40(10), pp.2148-2150; 2011
Abstract: The hydroxido-bridged dinuclear ruthenium complex 4, which is supported by Tp ligands, has been prepared from protonation of the oxido-bridged dinuclear ruthenium complex 3. Additional protonation of 4, affording the aqua-bridged dinuclear ruthenium complex 5 in situ, and subsequent treatment with NO gave rise to the dicationic dinitrosyl complex 2. These indicate completion of the NO reduction cycle on the dinuclear ruthenium complex.
URI: http://hdl.handle.net/10069/27396
ISSN: 14779226
DOI: 10.1039/c0dt01002b
PubMed ID: 20941446
Rights: © 2011 The Royal Society of Chemistry.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/27396

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