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The vibrational spectra and structures of hexachlorodisilazane and hexamethyldisilazane


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Title: The vibrational spectra and structures of hexachlorodisilazane and hexamethyldisilazane
Authors: Robinson, E.A. / Hamada, Keinosuke
Authors (alternative): 浜田, 圭之助
Issue Date: 29-Feb-1972
Publisher: 長崎大学教育学部
Citation: 長崎大学教育学部自然科学研究報告. vol.23, p.69-73; 1972
Abstract: The spectroscopic and structural investigations of haxachlorodisilazane and hexamethyldisilazane are reported. According to their spectra, the structure of those molecules seem to be D3d. Generally, a rigid D3d is indistinguishable from an internal rotating D′3h according to vibrational spectra. However, in this case, the molecules appear to be D′3h structure with free rotation of SiX3(X=Cl, Me) groups.
URI: http://hdl.handle.net/10069/33024
ISSN: 0386443X
Type: Departmental Bulletin Paper
Text Version: publisher
Appears in Collections:No. 23

Citable URI : http://hdl.handle.net/10069/33024

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