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An efficient method for selective oxidation of 1,2-diols in water catalyzed by Me2SnCl2


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Title: An efficient method for selective oxidation of 1,2-diols in water catalyzed by Me2SnCl2
Authors: William, Julius M. / Kuriyama, Masami / Onomura, Osamu
Issue Date: 14-Nov-2013
Publisher: Royal Society of Chemistry
Citation: RSC Advances, 3(42), pp.19247-19250; 2013
Abstract: Dimethyltin(iv)dichloride-catalyzed selective oxidation of 1,2-diols in water was achieved using dibromoisocyanuric acid (DBI) or Br2 as oxidants. The catalyst activates the 1,2-diol moiety through the formation of stannylene acetal in addition to enhancing selectivity. Various cyclic and acyclic 1,2-diol substrates have been selectively oxidized affording α-hydroxyketones in good to excellent yields. This method is safe and simple in operation.
URI: http://hdl.handle.net/10069/33980
DOI: 10.1039/c3ra42754d
Rights: © 2013 The Royal Society of Chemistry.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/33980

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