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The ideal porous structure of EDLC carbon electrodes with extremely high capacitance

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Nanoscale9_15643.pdf1.29 MBAdobe PDF公開予定日: 2018-10-28

タイトル: The ideal porous structure of EDLC carbon electrodes with extremely high capacitance
著者: Urita, K. / Urita, C. / Fujita, K. / Horio, K. / Yoshida, M. / Moriguchi, I.
発行日: 2017年10月28日
出版者: Royal Society of Chemistry
引用: Nanoscale, 9(40), pp.15643-15649; 2017
抄録: We propose an ideal porous structure of carbon electrodes for electric double-layer capacitors (EDLCs). The porous carbon successfully improved the gravimetric capacitance above ∼200 F g−1 even in an organic electrolyte by utilizing the carbon nanopore surface more effectively. High-resolution transmission electron microscopy images and X-ray diffraction patterns classified 15 different porous carbon electrodes into slit-shape and worm-like-shape, and the pore size distributions of the carbons were carefully determined applying the grand canonical Monte Carlo method to N2 adsorption isotherms at 77 K. The ratio of pores where solvated ions and/or desolvated ions can penetrate also has a significant effect on the EDL capacitance as well as the pore shape. The detailed study on the effect of porous morphologies on the EDLC performance indicates that a hierarchical porous structure with a worm-like shaped surface and a pore size ranging from a solvated ion to a solvent molecule is an ideal electrode structure.
URI: http://hdl.handle.net/10069/37899
ISSN: 20403364
DOI: 10.1039/C7NR05307J
権利: © 2017 The Royal Society of Chemistry
資料タイプ: Journal Article
原稿種類: author
出現コレクション:060 学術雑誌論文

引用URI : http://hdl.handle.net/10069/37899



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