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Palladium-catalyzed chemoselective anaerobic oxidation of N-heterocycle-containing alcohols


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Title: Palladium-catalyzed chemoselective anaerobic oxidation of N-heterocycle-containing alcohols
Authors: Kuriyama, Masami / Nakashima, Sho / Miyagi, Tsubasa / Sato, Kanako / Yamamoto, Kosuke / Onomura, Osamu
Issue Date: 7-Aug-2018
Publisher: Royal Society of Chemistry
Citation: Organic Chemistry Frontiers, 5(15), pp.2364-2369; 2018
Abstract: The palladium-catalyzed anaerobic oxidation for N-heterocycle-containing alcohols has been developed with chloroarenes as oxidants. In this process, primary and secondary alcohols were selectively oxidized even in the presence of cyclic amines as well as heteroarenes, and primary, secondary, and tertiary amino groups were found to be well tolerated. Moreover, a gram-scale chemoselective oxidation was achieved in addition to a double oxidation of a diamino diol.
URI: http://hdl.handle.net/10069/38545
ISSN: 20524110
DOI: 10.1039/C8QO00421H
Rights: © 2018 the Partner Organisations.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/38545

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