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Arrangement of a NO ligand and the neighboring sulfur-containing species on a dinuclear ruthenium complex by ligand substitution and linkage isomerism of a dimethyl sulfoxide ligand


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Title: Arrangement of a NO ligand and the neighboring sulfur-containing species on a dinuclear ruthenium complex by ligand substitution and linkage isomerism of a dimethyl sulfoxide ligand
Authors: Arikawa, Yasuhiro / Otsubo, Yuji / Nakayama, Tomofumi / Mitsuda, Naoto / Horiuchi, Shinnosuke / Sakuda, Eri / Umakoshi, Keisuke
Issue Date: 1-May-2019
Publisher: Elsevier B.V.
Citation: Inorganica Chimica Acta, 490, pp.45-50; 2019
Abstract: The substitution reactions of a NO-ligated dinuclear ruthenium complex with ammonium thiocyanate (NH4SCN), sulfur, and dimethyl sulfoxide (DMSO) gave the corresponding mononitrosyl dinuclear complexes, except for reaction with sulfur, where diastereomers of a S2-bridged tetranuclear complex along with a NO- and S2-bridged dinuclear complex were obtained. According to the scan rate dependent cyclic voltammograms, linkage isomerism of a dmso ligand on the dinuclear complex was revealed, and the linkage isomer was obtained from the chemical oxidation.
Keywords: Dinuclear / Linkage isomerism / Ruthenium / Substitution reaction / Sulfur
URI: http://hdl.handle.net/10069/38932
ISSN: 00201693
DOI: 10.1016/j.ica.2019.02.036
Rights: © 2019 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0 license.
Type: Journal Article
Text Version: author
Appears in Collections:Articles in academic journal

Citable URI : http://hdl.handle.net/10069/38932

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