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NAOSITE : Nagasaki University's Academic Output SITE > Faculty of Engineering > Bulletin > Reports of the Faculty of Engineering, Nagasaki University > Volume 30, No. 54 >

超音波の化学作用を利用した水溶液中における炭素侵入型パラジウムナノ粒子の調製


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Title: 超音波の化学作用を利用した水溶液中における炭素侵入型パラジウムナノ粒子の調製
Other Titles: Sonochemical Preparation of Palladium Nanoparticles with Interstitial Carbon in Aqueous Solution
Authors: 興津, 健二 / 田邉, 秀二 / 松本, 泰重
Authors (alternative): Okitsu, Kenji / Tanabe, Shuji / Matsumoto, Hiroshige
Issue Date: Jan-2000
Citation: 長崎大学工学部研究報告 Vol.30(54) p.91-96, 2000
Abstract: Sonochemical reduction of Tetrachloropalladate (II) ions in water were carried out in the presence of an organic compound such as surfactant, water soluble polymer and alcohol, and the nanoparticles of Pd metal were synthesized. From the results of the XRD analysis and so on, it was found that carbon atoms were present on an interstitial sites of the Pd lattice. The mechanism of carbon insertion and the control of the number of carbon atoms in the Pd particles are discussed. Our experimental results suggest that the PdC phase may have been formed unintentionally by the conventional preparation methods of colloidal Pd metals, and indicate out that phase identification should be done carefully, considering the influence of the carbon uptake on the catalytic activity and/or surface chemistry of the particles.
URI: http://hdl.handle.net/10069/5104
ISSN: 02860902
Type: Departmental Bulletin Paper
Appears in Collections:Volume 30, No. 54

Citable URI : http://hdl.handle.net/10069/5104

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