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NAOSITE : Nagasaki University's Academic Output SITE > Faculty of Education > Bulletin > Science bulletin of the Faculty of Education, Nagasaki University > No. 58 >

ルテニウム複核錯体被覆電極を用いた有機スズ化合物の電気化学的微量検出 : トリブチルスズ化合物の定性的分析

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Title: ルテニウム複核錯体被覆電極を用いた有機スズ化合物の電気化学的微量検出 : トリブチルスズ化合物の定性的分析
Other Titles: Detection of Organotin Compound at the Trace Level by Voltammetric Method with Binuclear Ruthenium Complex Coated Electrode
Authors: 星野, 由雅
Authors (alternative): Hoshino, Yoshimasa
Issue Date: 25-Mar-1998
Citation: 長崎大学教育学部自然科学研究報告. vol.58, p.15-22; 1998
Abstract: The electrochemical behavior of tributyltin (IV) chloride in 20% (v/v) methanol-water medium at the trace level has been investigated by differential pulse anodic stripping voltammetry with a bare glassy carbon (GC) electrode and a binuclear ruthenium complex, (μ-1,1,6,6-tetraacetyl-2,4-hexadiynato) bis[bis (2,2,6,6-tetramethyl-1,3-heptanedionato) ruthenium (III)], coated GC electrode. The tin compound exhibited an anodic peak at -0.70 V vs. Ag/AgCl on the voltammogram with the coated electrode, but the corresponding peak was not observed with the bare electrode. This is the first example of detection for organotin compounds by voltammetric methods without an Hg electrode.
URI: http://hdl.handle.net/10069/6179
ISSN: 0386443X
Type: Departmental Bulletin Paper
Appears in Collections:No. 58

Citable URI : http://hdl.handle.net/10069/6179

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