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Pd-Catalyzed Nucleophilic Allylation of Carbonyls with 1,3-Dienes


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Title: Pd-Catalyzed Nucleophilic Allylation of Carbonyls with 1,3-Dienes
Authors: Nakata, Masanori / Seguchi, Tetsuya / Toyoda, Kei / Kimura, Masanari / Tamaru, Yoshinao
Issue Date: 29-Jan-2008
Citation: Nagasaki Symposium on Nano-Dynamics 2008 (NSND2008), pp.49-50
Abstract: In the presence of Pd catalyst and triethylborane, aldehyde undergoes nucleophilic allylation with butadiene to provide dienyl homoallyl alcohols via bis-π-allylpalldium. The reaction feature depends on the kind of ligands; n-Bu3P promotes two molecules of aldehyeds to react with bis-π-allylpalldium and produces symmetrical dienyl diols, whereas bidentate ligands, dppf and dppe, provide dienyl homoallyl alcohols.
Description: Nagasaki Symposium on Nano-Dynamics 2008 (NSND2008) 平成20年1月29日(火)於長崎大学 Poster Presentation
Keywords: Palladium / Triethylborane / Diene / Aldehyde / Allylation
URI: http://hdl.handle.net/10069/9850
Type: Conference Paper
Appears in Collections:Nagasaki Symposium on Nano-Dynamics 2008 (NSND2008)

Citable URI : http://hdl.handle.net/10069/9850

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